FIFA World Cup 2014
The second stage heats up as two South American rivals clash -- host country Brazil, which topped Group A in the first round, faces off against Chile, which finished second in Group B. CBC, 10:45 a.m.
Chitty Chitty Bang Bang
In this high-flying 1968 musical comedy, a peculiar inventor transforms a broken racecar into a revolutionary flying vehicle. He takes his children and the lovely Miss Truly Scrumptious to a magical fantasy land. TCM, 12:45 p.m.
Catch a new episode of this eight-part mini-series based on the real-life of CIA counter-intelligence officer Sandy Grimes. In this instalment, Sandy has a run-in with a senior officer tasked with reviewing their operation. ABC, 8 p.m.
Take a close look at real murder cases from angles not reported in the news. George Smith disappeared while on his honeymoon cruise in 2005, and now a video has resurfaced that could point to what happened to the newlywed. CBS, 9 p.m.