Trophy wife-turned-teacher Meredith Davis (Ari Graynor) is up to no good in two new back-to-back episodes. The series, based on the Cameron Diaz comedy, also stars Sara Gilbert as Meredith's socially awkward colleague and Kristin Davis as her perky foil. 7 p.m., CBS
More questions are brought to light for CIA agent Sandra Grimes (Jodie Whittaker) in a new episode of this intriguing miniseries. The show is based on actual CIA accounts, as told by the real Sandra Grimes and her fellow officer, Jeanne Vertefeuille. 8 p.m., ABC
Sex Sent Me to the E.R.
Catch the latest list of bizarre and often comical injuries sustained behind closed doors in this new episode. Actors re-enact real-life accidents and calamities caused by nocturnal escapades that have landed couples in the emergency room. TLC, 8 p.m.
A past associate of Red's (James Spader), crime lord Mako Tanida (Hoon Lee), is given as the next name on the Blacklist. Tom (Ryan Eggold), meanwhile, confronts Jolene (Rachel Brosnahan) for interfering with his mission. NBC, 9 p.m.